Bis(diethylamido-κN)(diethylamine-κN)bis(2,6-diisopropylphenylamido-κN)zirconium(IV)
نویسندگان
چکیده
In the title compound, [Zr(C(12)H(18)N)(2)(C(4)H(10)N)(2)(C(4)H(11)N)] or [Zr(HNC(6)H(3) (i)Pr(2))(2)(NEt(2))(2)(HNEt(2))], which was obtained by the reaction of Zr(NEt)(4) with (i)Pr(2)C(6)H(3)NH(2), the Zr(IV) atom is in a trigonal-bipiramidal geometry in which the N atoms from two (i)Pr(2)C(6)H(3)NH and one NEt(2) ligand occupy the equatorial positions, and the N atoms of an NEt(2) and an Et(2)NH ligand occupy the apical positions. An intra-molecular N-H⋯N contact occurs. There are two independent molecules in the asymmetric unit.
منابع مشابه
Bis[2,6-bis(1-methyl-1H-benzimidazol-2-yl-κN 3)pyridine-κN]zinc dipicrate methanol disolvate
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